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51.
Martin Streloke 《Environmental Sciences Europe》1998,10(5):312-314
This article deals with the question of how to consider data from aquatic mesocosm tests in the registration procedure of plant protection products. The legal framework is presented. This type of test must fulfill special methodological requirements in order to become a valuable tool for risk assessment. If this is the case, the data from mesocosm studies is more important than that from laboratory tests. Such studies must only be submitted if the risk assessment on the basis of standard laboratory tests indicate a risk for aquatic organisms. 相似文献
52.
Behrends A Riediger S Grube S Poeggeler B Haldar C Hardeland R 《Journal of environmental science and health. Part. B》2007,42(6):599-606
The redox-active quinalphos main metabolite, 2-hydroxyquinoxaline, is particularly effective under excitation by light. We have studied the photocatalytic destruction of melatonin and its precursors, because the cytoprotective indoleamine has been detected in high quantities in mammalian skin. In photooxidation reactions, in which melatonin, N-acetylserotonin and serotonin are destroyed by 2-hydroxyquinoxaline, the photocatalyst is virtually not consumed. Rates of melatonin and serotonin destruction are not changed by the singlet oxygen quencher 1,4-diazabicyclo-(2,2,2)-octane, indicating that this oxygen species is not involved in the primary reactions, so that the persistence of 2-hydroxyquinoxaline has to be explained by redox cycling. This should imply formation of an organic radical, presumably the quinoxaline-2-oxyl radical, from which 2-hydroxyquinoxaline is regenerated by electron abstraction from indolic radical scavengers. Electron donation by 2-hydroxyquinoxaline is demonstrated by reduction of the 2,2'-azino-bis-(3-ethylbenzthiazolinyl-6-sulfonic acid) cation radical under ultrasound excitation. The compound 2-hydroxyquinoxaline interacts with the specific superoxide anion scavenger Tiron. Formation of oligomeric products from melatonin and serotonin is strongly inhibited by sodium dithionite. Products from photocatalytic indolamine conversion are predominantly dimers and oligomers. No kynuramines were detected in the case of serotonin oxidation, and melatonin's otherwise prevailing oxidation product N(1)-acetyl-N(2)-formyl-5-methoxykynuramine, another cytoprotective metabolite, is only formed in relatively small quantities. The proportion between products from melatonin is changed by 1,4-diazabicyclo-(2,2,2)-octane: singlet oxygen, also formed under the influence of excited 2-hydroxyquinoxaline, only affects secondary reactions. 相似文献
53.
Rudolf Brenneis Hubertus Wichmann Regina Sprenger Astrid Eickhoff Ralf Bock Tina Dettmer Burkhard Baeck Christian Reger Müfit Bahadir 《Environmental Sciences Europe》2006,18(2):95-101